Acid rain forms when sulphur dioxide and nitrogen oxides react with water vapour and other chemicals in the atmosphere to produce sulphuric and nitric acids. These acids then fall to the ground with rain, snow or dust. Because the stem mentions burning fossil fuels and industrial processes,the combination of sulphur dioxide and nitrogen oxides best explains the phenomenon.
Option A:
Carbon monoxide and ozone are important air pollutants, but they do not directly form strong acids responsible for acid rain. Carbon monoxide mainly affects human health, and tropospheric ozone is a component of photochemical smog. Therefore this pair does not match the primary chemical cause described.
Option B:
Sulphur dioxide and nitrogen oxides are released in large quantities from coal based power plants, industrial boilers and vehicles. Once in the atmosphere, they undergo oxidation and acid formation, leading to acid deposition. This clearly aligns with the explanation of acid rain in the question.
Option C:
Methane and ammonia can participate in atmospheric chemistry and contribute to other environmental issues such as eutrophication and greenhouse effects. However, they are not the principal precursors of acid rain in most contexts. Hence this option is not correct.
Option D:
Chlorofluorocarbons are associated mainly with ozone layer depletion, and helium is a chemically inert gas. Neither plays a significant role in generating acid rain, so this pair is inappropriate for the stem.
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